A method of an electronic device is provided. The method includes obtaining, from a memory of the electronic device, information indicating a usage relationship between distinct states of a user of the electronic device and at least one body part, identifying a first state of the user corresponding to a first function among a plurality of functions executable by the electronic device, identifying an event for executing a second function different from the first function, comparing, in response to identifying the event, a first body part used by the user associated with the first state and a second body part used by the user associated with a second state corresponding to the second function, based on the obtained information, and executing, in response to the identified event, a third function indicated in the information as being associated with the second function, based on a result of the comparing.