The present invention relates to a method of forming an optical fiber precursor including: forming an alkali metal doped tube; inserting an optical fiber core rod within the alkali metal doped tube; forming a cladding jacket around the alkali metal doped tube; and diffusing an alkali metal from the alkali metal doped tube through a surface of the optical fiber core rod. The present invention further relates to an optical fiber preform having: an optical fiber core rod; an alkali metal doped tube surrounding the optical fiber core rod; and a cladding jacket surrounding the alkali metal doped tube.