An article according to an exemplary embodiment of this disclosure, among other possible things includes a substrate and a barrier layer on the substrate. The barrier layer includes a bond coat comprising a matrix, diffusive particles disposed in the matrix, and gettering particles disposed in the matrix; and a topcoat including a constituent that is reactive with calcium-magnesium-alumino-silicate (CMAS). An article and a method applying a calcium-magnesium-alumino-silicate (CMAS)-resistant topcoat are also disclosed.