A screw structure includes a screw and a washer mounted on the screw. The bottom face of the screw head is provided with a plurality of pressing portions. Each of the pressing portions has a top provided with a first plane and a bottom provided with a second plane having an area smaller than that of the first plane. Each of the pressing portions is provided with a first inclined face and a first steep arcuate face. The first inclined face is directed toward a clockwise direction of the screw when the screw is screwed. The first steep arcuate face is directed toward the external thread. When the screw is screwed into an article, the pressing portions press the washer, and an outer diameter of the washer is expanded outward and forms an expansion.