Provided is an industrially advantageous method for producing an alkanedisulfonic acid compound easily and inexpensively with a high yield. The present invention is a method for producing an alkanedisulfonic acid compound comprising reacting at least one alkanesulfonic acid compound having a specific structure and at least one complex having a Lewis base and sulfur trioxide to thereby obtain an alkanedisulfonic acid compound. According to the production method of the present invention, it is possible to produce an alkanedisulfonic acid compound easily and inexpensively with a high yield, which is industrially advantageous.