Invention Publication
- Patent Title: METHOD FOR PRODUCING CALCIUM SULFATE HEMIHYDRATE WHISKERS BY USING FERMENTATION BROTH FOR PRODUCING LACTIC ACID WITH CALCIUM SALT METHOD AS RAW MATERIAL AND SYNCHRONOUSLY RECOVERING LACTIC ACID MONOMER
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Application No.: US17616648Application Date: 2021-02-03
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Publication No.: US20240025756A1Publication Date: 2024-01-25
- Inventor: Zhengxiang WANG , Dandan NIU , Kangming TIAN , Fuping LU , Chunli SHEN
- Applicant: TIANJIN UNIVERSITY OF SCIENCE & TECHNOLOGY
- Applicant Address: CN Tianjin 300457
- Assignee: TIANJIN UNIVERSITY OF SCIENCE & TECHNOLOGY
- Current Assignee: TIANJIN UNIVERSITY OF SCIENCE & TECHNOLOGY
- Current Assignee Address: CN Tianjin 300457
- Priority: CN 2011613171.3 2020.12.31
- International Application: PCT/CN2021/074953 2021.02.03
- Date entered country: 2021-12-04
- Main IPC: C01F11/46
- IPC: C01F11/46 ; C07C51/42

Abstract:
The disclosure discloses a method for producing α-calcium sulfate hemihydrate whiskers by using fermentation broth for producing lactic acid with a calcium salt method as a raw material and synchronously recovering a lactic acid monomer. The method comprises the following steps: 1) after fermentation of lactic acid is ended, heating fermentation broth; 2) stirring, and adding sulfuric acid for reaction; 3) after the reaction is ended, filtering and collecting a solid part, namely α-calcium sulfite hemihydrate whiskers, and collecting a liquid part, namely a free lactic acid solution containing the lactic acid monomer; and 4) washing and drying the obtained α-calcium sulfate hemihydrate whiskers to obtain a α-calcium sulfate hemihydrate whisker finished product, filtering and concentrating the obtained free lactic acid solution to obtain a lactic acid crude product, and refining the lactic acid crude product to obtain a high-purity lactic acid monomer. The disclosure can replace the efficient separation of lactic acid in production of lactic acid with the existing calcium salt method and high value-added transformation of a calcium sulfite byproduct, thereby significantly reducing the refining cost of lactic acid and formation of wastes and facilitating improvement of lactic acid production quality and simplification of a post-extraction process technology.
Information query
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