The present invention relates to a stable aqueous agrochemical composition in form of a liquid herbicidal composition comprising water, a water soluble herbicidal compound and a specific mixture of organic solvents for use in agricultural application methods. The liquid herbicidal composition comprises (A) 5 to 45 weight %, based on the total weight of the composition, of one herbicidal compound selected from glufosinate, a salt thereof, preferably the ammonium salt, and/or its respective (L-)isomers (B) a mixture of two alcoholic solvents, a monohydric alcohol (B.1) and a polyhydric solvents (B.2), wherein (B.1) at least one monohydric alcohol B.1 is selected from methanol, ethanol or isopropanol, or any mixture thereof; and (B.2) at least one polyhydric alcohol B.2 is selected from 1,2-propylene glycol or glycerol, or a mixture thereof; (C) water and (D) 15 to 70 weight %, based on the total weight of the composition, of at least one compound of formula (I) [R-(A)x-OS)3−]-M+ (I); wherein R is C10-C16-alkyl, C10-C16-alkenyl, or C10-C16-alkynyl; A is a group wherein RA, RB, RC, and RD are selected from H, CH3, or CH2CH3 with the proviso that the sum of C-atoms of RA, RB, RC, and RD is 0, 1 or 2; M+ is a monovalent cation selected from the group of alkali metal ions, NH4+ and an ammonium cation of a primary, secondary or tertiary amine or a quaternary ammonium cation, or a mixture thereof; and x is a number selected from 0 to 10.