The present application provides a secondary battery, including a positive electrode, a negative electrode with a negative electrode material layer, and a non-aqueous electrolyte, the negative electrode material layer comprises a negative electrode active material, and the negative electrode active material comprises a silicon-based material;
the non-aqueous electrolyte comprises a solvent, an electrolyte salt and an additive, the additives comprises a compound represented by structural formula 1;




wherein n is 0 or 1, A is selected from C or O, X is selected from






R1 and R2 are each independently selected from H,
R1 and R2 are not selected from H at the same time, and X, R1 and R2 comprise at least one sulfur atom;








the secondary battery meets the following requirements:







0
.
2

⁢
1

≤


m
*
n
*
r

S

≤
40

;




and 40%≤m≤90%, 0.05%≤n≤2%, 1.2 g/cm3≤r≤1.8 g/cm3, 5%≤S≤30%.