A charging system includes a power input part, an inverter, a DC bus, at least one charging device, a first bidirectional energy storage module, a second bidirectional energy storage module and an intelligent controller. The charging device includes a DC/DC converter and a charging gun. A first bidirectional DC/DC converter of the first bidirectional energy storage module receives and converts the DC power from the inverter for charging a first battery, or converts a first storage electric energy of the first battery for the charging device. A second bidirectional DC/DC converter of the second bidirectional energy storage module receives and converts the electric energy outputted by the DC/DC converter of the charging device for charging a second battery, or converts a second storage electric energy of the second battery for the charging device. The intelligent controller controls operations of the first bidirectional DC/DC converter and the second bidirectional DC/DC converter.