- 专利标题: COMPOSITIONS, COMPRISING SILVER NANOPLATELETS
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申请号: US18275435申请日: 2022-01-31
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公开(公告)号: US20240309174A1公开(公告)日: 2024-09-19
- 发明人: Nikolay A. GRIGORENKO , Andre OSWALD
- 申请人: BASF SE
- 申请人地址: DE Ludwigshafen Am Rhein
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen Am Rhein
- 优先权: EP 154989.4 2021.02.03
- 国际申请: PCT/EP2022/052247 2022.01.31
- 进入国家日期: 2023-08-02
- 主分类号: C08K3/08
- IPC分类号: C08K3/08 ; B22F1/054 ; B22F1/0545 ; B22F9/24 ; B22F10/12 ; B33Y70/00
摘要:
The present invention relates to radically curable compositions, comprising (A) silver nanoplatelets, (B) one reactive diluent comprising 1 to 4 (meth)acrylate groups; (C) one, or more urethane (meth)acrylates (C), which are obtainable by reaction of the following components:
(a) at least one isocyanate having two isocyanate groups,
(b) at least one polyalkylene oxide polyether having at least 2 hydroxyl groups,
(c) at least one hydroxy-functional (meth)acrylate having one hydroxyl group and one (meth)acrylate group,
(d) at least one compound having at least one isocyanate reactive group and at least one acid function,
(e) if component (d) is present, optionally at least one basic compound which is present for neutralization or partial neutralization of the acid groups of component (d),
(f) optionally at least one monoalcohol having one hydroxy function, and
(g) optionally at least one compound having at least one primary and/or secondary amino group;
(D) one, or more photonitiators; printing inks containing the compositions and their use for the production security products. Coatings obtained after curing of the compositions, show one color, when observed in transmission and another color, when observed in reflection on both sides of the cured coating. The metal-like reflection of the coatings may be further enhanced by the presence of surfactants.
(a) at least one isocyanate having two isocyanate groups,
(b) at least one polyalkylene oxide polyether having at least 2 hydroxyl groups,
(c) at least one hydroxy-functional (meth)acrylate having one hydroxyl group and one (meth)acrylate group,
(d) at least one compound having at least one isocyanate reactive group and at least one acid function,
(e) if component (d) is present, optionally at least one basic compound which is present for neutralization or partial neutralization of the acid groups of component (d),
(f) optionally at least one monoalcohol having one hydroxy function, and
(g) optionally at least one compound having at least one primary and/or secondary amino group;
(D) one, or more photonitiators; printing inks containing the compositions and their use for the production security products. Coatings obtained after curing of the compositions, show one color, when observed in transmission and another color, when observed in reflection on both sides of the cured coating. The metal-like reflection of the coatings may be further enhanced by the presence of surfactants.
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