发明授权
US3655788A Phosgene as a novel catalyst for the abnormal addition of hbr to alpha-olefins 失效
作为乙酰胆碱异丙酯添加剂的新型催化剂

Phosgene as a novel catalyst for the abnormal addition of hbr to alpha-olefins
摘要:
LONG CHAIN ALPHA-OLEFINS OF AT LEAST SIX CARBON ATOMS UNDERGO ANTI-MARKOWNIKOFF ADDITION WHEN TREATED WITH HYDROGEN BROMIDE IN THE PRESENCE OF PHOSGENE TO PRODUCE PRIMARY ALKYL BROMIDES. THIS INVENTION RELATES TO THE PREPARATION OF ALKYL BROMIDES BY ANTI-MARKOWNIKOFF, OR FREE RADICAL ADDITION OF HYDROGEN BROMIDE TO ALPHA-OLEFINIC HYDROCARBONS. MORE PARTICULARLY, THE INVENTION RELATES TO A NOVEL CATALYST FOR EFFECTING THIS ADDITION.
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