发明授权
- 专利标题: Phosgene as a novel catalyst for the abnormal addition of hbr to alpha-olefins
- 专利标题(中): 作为乙酰胆碱异丙酯添加剂的新型催化剂
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申请号: US3655788D申请日: 1969-07-03
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公开(公告)号: US3655788A公开(公告)日: 1972-04-11
- 发明人: THOMAS ROBERT M , GERNS FRED R
- 申请人: GREAT LAKES CHEMICAL CORP
- 专利权人: Great Lakes Chemical Corp
- 当前专利权人: Great Lakes Chemical Corp
- 优先权: US83906469 1969-07-03
- 主分类号: C07C17/08
- IPC分类号: C07C17/08
摘要:
LONG CHAIN ALPHA-OLEFINS OF AT LEAST SIX CARBON ATOMS UNDERGO ANTI-MARKOWNIKOFF ADDITION WHEN TREATED WITH HYDROGEN BROMIDE IN THE PRESENCE OF PHOSGENE TO PRODUCE PRIMARY ALKYL BROMIDES. THIS INVENTION RELATES TO THE PREPARATION OF ALKYL BROMIDES BY ANTI-MARKOWNIKOFF, OR FREE RADICAL ADDITION OF HYDROGEN BROMIDE TO ALPHA-OLEFINIC HYDROCARBONS. MORE PARTICULARLY, THE INVENTION RELATES TO A NOVEL CATALYST FOR EFFECTING THIS ADDITION.
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