发明授权
- 专利标题: Hydrocracking process with fluorine treat to avoid condensed polyaromatics
- 专利标题(中): 具有氟化物的水解过程避免冷凝多糖
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申请号: US3725244D申请日: 1971-10-13
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公开(公告)号: US3725244A公开(公告)日: 1973-04-03
- 发明人: SCHUTT H
- 申请人: SHELL OIL CO
- 专利权人: Shell Oil Co
- 当前专利权人: Shell Oil Co
- 优先权: US18840871 1971-10-13
- 主分类号: C10G47/02
- IPC分类号: C10G47/02 ; B01J23/90 ; B01J23/94 ; B01J27/32 ; B01J38/42 ; C10G47/12 ; C10G65/10 ; C10G9/16 ; B01J11/80 ; C10G13/06
摘要:
A TWO-STAGE HYDROCRACKING PROCESS EMPLOYING RECYCLE OF HIGH BOILING, SECOND STAGE PRODUCT TO SECOND STAGE FEED AND A SECOND STAGE CATALYST CONTAINING AN IRON GROUP HYDROGENATIVE METAL SUPPORTED ON AN AMORPHOUS SILICAALUMINA-FLUORINE ACID-ACTING BASE ISIMPROVED TO AVOID FORMATION OF POLYAROMATIC COMPOUNDS IN THE HIGH BOILING PRODUCT BY (A) FIRST DISCONTINUING THE FLOW OF HYDROCARBON FEED TO THE SECOND-STAGE, (B) THEN CONTACTING THE SECOND STAGE CATALYST WITH OXYGEN, (C) CONTACTING THE OXIDIZED SECOND STAGE CATALYST WITH A SULFIDING COMPOUND AT CONDITIONS TO CONVERT THE IRON GROUP METAL COMPONENT TO A SULFIDE FORM, (D) CONTACTING THE SECOND STAGE CATALYST WITH FROM ABOUT 0.001% TO ABOUT 0.2 WT. OF CATALYST OF FLUORINE IN THE FORM OF A VAPOR PHASE FLUORIDING COMPOUND AT A TEMPERATURE OF FROM 350* TO 1100*F., AND (E) RE-ESTABLISHING THE FLOW OF HYDROCARBON FEED TO THE SECOND-STAGE.
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