发明授权
US3950311A Process for the preparation of polycaprolactam which can be dyed with
cationic dyes
失效
制备可与阳离子染色剂聚合的聚碳酸酯的方法
- 专利标题: Process for the preparation of polycaprolactam which can be dyed with cationic dyes
- 专利标题(中): 制备可与阳离子染色剂聚合的聚碳酸酯的方法
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申请号: US449496申请日: 1974-03-08
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公开(公告)号: US3950311A公开(公告)日: 1976-04-13
- 发明人: Eduard Radlmann , Jurgen Schramm , Gunter Nischk
- 申请人: Eduard Radlmann , Jurgen Schramm , Gunter Nischk
- 申请人地址: DT Leverkusen
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DT Leverkusen
- 优先权: DT2311982 19730310
- 主分类号: C08G69/00
- IPC分类号: C08G69/00 ; C08G69/16 ; C08G69/42
摘要:
This invention relates to a process for the preparation of a polycaprolactam which can be dyed with basic dyes and worked up from the melt to form products such as fibers or foils. The polycaprolactams contain structural elements of the formulae ##SPC1##WhereinM denotes an alkali metal andR denotes an alkylene group containing 4 - 12 carbon atoms.The process of the production of the polycaprolactams comprises precondensing the alkali metal salt of a dialkyl ester of 5-sulphoisophthalic acid in aqueous solution with an excess of hexamethylene diamine and adding caprolactam and an equivalent quantity based on the hexamethylene diamine excess of an aliphatic dicarboxylic acid to the resulting aqueous precondensate and polycondensing the mixture.
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