Invention Grant
- Patent Title: Process for the esterification of terephthalic acid in the gas phase
- Patent Title (中): 在气相中对苯二甲酸酯化的方法
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Application No.: US420307Application Date: 1973-11-29
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Publication No.: US3972912APublication Date: 1976-08-03
- Inventor: Horst-Dieter Wulf , Ferdinand List , Friedrich-August Orlowski , Norbert Wilke , Emmerich Pflegerl
- Applicant: Horst-Dieter Wulf , Ferdinand List , Friedrich-August Orlowski , Norbert Wilke , Emmerich Pflegerl
- Assignee: Chemische Werke Huls Aktiengesellschaft
- Current Assignee: Chemische Werke Huls Aktiengesellschaft
- Priority: DT2261333 19721215
- Main IPC: C07C69/82
- IPC: C07C69/82 ; B01J8/04 ; B01J19/18 ; B01J19/28 ; C07C67/08
Abstract:
Dimethyl terephthalate is prepared by the continuous esterification of terephthalic acid in the gas phase by evaporating solid terephthalic acid in a pre-reactor by means of a hot methanol vapor stream, conducting the gas mixture through a solid bed catalyst in a follow-up reactor, and recirculating a portion of the reaction product to the pre-reactor. After the pre-reactor the terephthalic acid dispersed in the methanol gas phase is heated and vaporized in one or more consecutive heat exchangers followed by one or more dwell period lengths and immediately heated to the esterification temperature prior to entry into the follow-up reactor.
Public/Granted literature
- US5058659A Process for the production of steel having a varying chemical composition in the cross-section Public/Granted day:1991-10-22
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