发明授权
US4008266A Coupling of aromatic compounds in the presence of molecular oxygen, a mercuric oxyanion compound, and a group VIII metal or group VIII metal oxyanion compound 失效
在分子氧存在下芳族化合物的偶联,汞氧阴离子化合物和VIII族金属或VIII族金属氧阴离子化合物

Coupling of aromatic compounds in the presence of molecular oxygen, a
mercuric oxyanion compound, and a group VIII metal or group VIII metal
oxyanion compound
摘要:
A catalytic process in which molecular oxygen is used to couple aromatic compounds to form a variety of polyaromatic compounds is disclosed. The process comprises reacting monoaromatic compounds in the presence of molecular oxygen and a catalyst system comprising a mercuric oxyanion compound, a Group VIII metal, or metal oxyanion compound and optionally a redox reagent consisting of a soluble salt of a multivalent metal having an oxidation potential greater than that of the Group VIII metal.
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