A method of preparing synthetic resin film having high writability and printability which comprises the steps of (I) carrying out reaction by either of the following two processes:The process A of reacting together1. alicyclic polybasic acid or anhydrides thereof, (2) polypoxides containing at least two epoxy groups and (3) a compound selected from the group consisting of (a) unsaturated monobasic acid, (b) glycidyl compounds containing a radical polymerizable unsaturated bond and (c) unsaturated polybasic acid.The process B of reacting together1. at least one compound selected from the group consisting of (a) polyepoxides containing at least two epoxy groups and (b) alicyclic polybasic acid or anhydrides thereof and (2) compounds containing vinyl and hydroxyl groups in the molecule; (II) mixing the unsaturated polyester compounds obtained in above process with fillers; (III) coating the mixture on the surface of synthetic resin film; and (IV) subjecting said coating to photopolymerization by irradiating ultraviolet rays.