发明授权
US4029560A Process for producing
.alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene
失效
制备{60,{60,{60,{60 {40,{60 {40,{60 {40-六氯二氧化碳
- 专利标题: Process for producing .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene
- 专利标题(中): 制备{60,{60,{60,{60 {40,{60 {40,{60 {40-六氯二氧化碳
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申请号: US671698申请日: 1976-03-29
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公开(公告)号: US4029560A公开(公告)日: 1977-06-14
- 发明人: Shigeo Yoshinaka , Masaharu Doya , Seiiji Uchiyama , Sadao Nozaki
- 申请人: Shigeo Yoshinaka , Masaharu Doya , Seiiji Uchiyama , Sadao Nozaki
- 申请人地址: JA Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JA Tokyo
- 优先权: JA50-39587 19750401
- 主分类号: C07C17/00
- IPC分类号: C07C17/00 ; C07C17/14 ; C07C22/04 ; C07C51/00 ; C07C51/60 ; C07C63/15 ; C07C63/30 ; C07C67/00 ; C08G69/32 ; B01J1/10
摘要:
This invention concerns to a process for .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene by reacting m-xylene or p-xylene or a partially chlorinated product thereof with chlorine under the irradiation of ultraviolet rays, the process comprising (1) a first-step chlorination reaction which is carried out in the presence of .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene as a solvent added at the initial stage of the reaction, and continued until a compound convertible to .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene by chlorination becomes substantially absent in the reaction mixture, and (2) a second-step chlorination reaction which is continued from the first-step chlorination and carried out to convert difficulty-separable by-products present in the reaction mixture to easily-separable compounds. This invention also concerns to a process for producing an aromatic dicarboxylic acid chloride which comprise reacting the resulting .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene with isophthalic acid or terephthalic acid.