A process for the electrodeposition of metal onto the particles of a fluidised bed cathode is of particular use in the electro-winning of metals. Agglomeration of particles is substantially avoided by the elimination of sharp corners within the portion of the cell where there is electrodeposition and by the removal of particles from the fluidised bed cathode before they reach a size where they tend to lodge adjacent structural surfaces within the cathode compartment. Flow of electrolyte into the base of the cathode compartment may conveniently be distributed by a porous plate or a "V" shaped trough.