发明授权
- 专利标题: Polymerization of cyclic olefins
- 专利标题(中): 环烯烃的聚合
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申请号: US652884申请日: 1976-01-27
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公开(公告)号: US4046710A公开(公告)日: 1977-09-06
- 发明人: Gunther Lehnert , Dieter Maertens , Gottfried Pampus , Josef Witte
- 申请人: Gunther Lehnert , Dieter Maertens , Gottfried Pampus , Josef Witte
- 申请人地址: DT
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DT
- 优先权: DT2332563 19730627
- 主分类号: B01J31/34
- IPC分类号: B01J31/34 ; C08F4/62 ; C08G61/08 ; C08F4/78
摘要:
A process for the preparation of a catalyst for the polymerization and copolymerization of cyclic olefins which have 4, 5, 7 or more ring carbon atoms and at least one olefinic double bond in the ring, fromA. at least one halide or oxyhalide of molybdenum, preferably with molybdenum in the oxidation state +5,B. at least one 2-halo alcohol andC. at least one aluminium compound in the molar ratio of a : b = 1 : 1 to 1 : 10 and a : c = 1 : 0.5 to 1 : 30,Characterized in that the molybdenum halide or oxyhalide and the 2-halo alcohol are reacted with the exclusion of solvents or in the presence of chlorinated solvents which are inert towards the molybdenum salt and in which the molybdenum salt is soluble to an extent of at least 0.01 molar, and the aluminium alkyl compound is added, optionally in the presence of the monomers.
公开/授权文献
- US5708073A Non-aqueous, base-degradable polyurethane 公开/授权日:1998-01-13
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