发明授权
US4057536A Process for preparing wholly aromatic polyamides by mixing solid particulate reactants and polymerizing 失效
通过混合固体颗粒反应物和聚合制备全芳族聚酰胺的方法

  • 专利标题: Process for preparing wholly aromatic polyamides by mixing solid particulate reactants and polymerizing
  • 专利标题(中): 通过混合固体颗粒反应物和聚合制备全芳族聚酰胺的方法
  • 申请号: US648986
    申请日: 1976-01-14
  • 公开(公告)号: US4057536A
    公开(公告)日: 1977-11-08
  • 发明人: Rufus S. Jones, Jr.
  • 申请人: Rufus S. Jones, Jr.
  • 申请人地址: NY New York
  • 专利权人: Celanese Corporation
  • 当前专利权人: Celanese Corporation
  • 当前专利权人地址: NY New York
  • 主分类号: C08G69/32
  • IPC分类号: C08G69/32
Process for preparing wholly aromatic polyamides by mixing solid
particulate reactants and polymerizing
摘要:
An improved process is provided for preparing wholly aromatic polyamides from solid monomers; particularly, aromatic diamines and aromatic dicarboxylic acid halides. The solid monomers in particulate form are first mixed in the substantial absence of oxygen and in the absence of a solvent or diluent to prepare a uniform monomer mixture having a desired stoichiometry prior to the initiation of the polymerization reaction. The uniform monomer mixture is thereafter polymerized in the presence of an appropriate solvent as herein defined.
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