- 专利标题: Hydroformylation of olefins
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申请号: US828123申请日: 1977-08-26
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公开(公告)号: US4158020A公开(公告)日: 1979-06-12
- 发明人: Adin L. Stautzenberger , James L. Paul , Jerry D. Unruh
- 申请人: Adin L. Stautzenberger , James L. Paul , Jerry D. Unruh
- 申请人地址: NY New York
- 专利权人: Celanese Corporation
- 当前专利权人: Celanese Corporation
- 当前专利权人地址: NY New York
- 主分类号: C07C27/20
- IPC分类号: C07C27/20 ; B01J31/22 ; C07C27/00 ; C07C45/50 ; C07C67/00 ; C07C45/08
摘要:
Olefins are converted to aldehydes and/or alcohols having one more carbon atom than the olefin by reacting the olefin with carbon monoxide and hydrogen in the presence of an in situ formed catalytic complex of a Group VIII metal, carbon monoxide and a trivalent ligand, the metal being introduced into the reaction zone in the form of a solution of a water-soluble inorganic salt dissolved in a solvent comprised of at least 40% by volume of a polyalkylene glycol, the polyalkylene glycol acting as a coupling agent preventing precipitation of the metal prior to formation of the catalyst complex.