发明授权
US4159233A Cathodic electrocoating process for forming resinous coating using an
aqueous dispersion of polyamino polyhydroxy polyether resinous adduct
and acid-functional aminoplast
失效
使用聚氨基多羟基聚醚树脂加合物和酸官能氨基塑料的水性分散体形成树脂涂层的阴极电泳工艺
- 专利标题: Cathodic electrocoating process for forming resinous coating using an aqueous dispersion of polyamino polyhydroxy polyether resinous adduct and acid-functional aminoplast
- 专利标题(中): 使用聚氨基多羟基聚醚树脂加合物和酸官能氨基塑料的水性分散体形成树脂涂层的阴极电泳工艺
-
申请号: US874809申请日: 1978-02-03
-
公开(公告)号: US4159233A公开(公告)日: 1979-06-26
- 发明人: Vincent W. Ting , James M. Evans
- 申请人: Vincent W. Ting , James M. Evans
- 申请人地址: OH Cleveland
- 专利权人: SCM Corporation
- 当前专利权人: SCM Corporation
- 当前专利权人地址: OH Cleveland
- 主分类号: C08G59/14
- IPC分类号: C08G59/14 ; C08G59/50 ; C09D5/44 ; C09D163/00 ; C09D163/02 ; C25D13/06
摘要:
An acid-solubilized aqueous dispersion particularly suitable for use in the cathodic electrocoating art and stable up to pH of about 9 comprises the product of reacting substantially all of the epoxide groups of a polyether diepoxide with from about 1.25 to 2 moles of a polyamine having from 2 to 5 amine groups to form a precursor adduct and subsequently reacting this precursor adduct with about 0.2 to 2 moles of a mono-epoxide having a hydrolysis-resistant normal alkyl group of at least 4 carbon atoms to form a substantially epoxy-free polyamino polyhydroxy polyether resinous adduct, a sufficient proportion of the amine groups of said polyamine being primary or secondary to provide an amino hydrogen for reaction with every epoxide group of both the diepoxide and the mono-epoxide, and about 0.05 to 0.4 weight parts (per part of the resinous adduct) of an aminoplast resin having at least about one gram-equivalent of carboxylic acid groups with pK.sub.a from about 2 to 6 per 1,000 grams of aminoplast resin for catalyzing heat-induced curing of the resin mixture. The coatings cathodically electrodeposited from such dispersions exhibit superior corrosion and detergent resistance when cured at moderate temperatures.
公开/授权文献
信息查询