Invention Grant
US4168284A Alpha olefin isomerization in preparing alkane phosphonic acids and intermediates 失效
制备烷烃膦酸和中间体时的α-烯烃异构化

Alpha olefin isomerization in preparing alkane phosphonic acids and
intermediates
Abstract:
Preparation of long chain alkane phosphonic acids involves reacting alpha olefin with macroreticular strong acid cation exchange resin to isomerize the olefin, reacting resulting internally unsaturated olefin with dimethylphosphite to produce non-terminally substituted alkanephosphonic acid dimethyl ester, and demethylating with anhydrous hydrogen chloride or hydrogen bromide.
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