发明授权
- 专利标题: Chlorine and iron oxide from ferric chloride--process and apparatus
- 专利标题(中): 氯化铁和氧化铁 - 工艺和设备
-
申请号: US899696申请日: 1978-04-24
-
公开(公告)号: US4174381A公开(公告)日: 1979-11-13
- 发明人: James W. Reeves , Robert W. Sylvester , David F. Wells
- 申请人: James W. Reeves , Robert W. Sylvester , David F. Wells
- 申请人地址: DE Wilmington
- 专利权人: E. I. Du Pont de Nemours & Co.
- 当前专利权人: E. I. Du Pont de Nemours & Co.
- 当前专利权人地址: DE Wilmington
- 主分类号: C01G49/02
- IPC分类号: C01G49/02 ; B01J8/38 ; C01B7/03 ; C01G49/06
摘要:
An improved industrial process and apparatus are provided for producing chlorine and iron oxide in a multi-stage recirculating-fluidized-bed reactor wherein ferric chloride in the vapor phase is reacted with an excess of oxygen at temperatures from 550.degree. to 800.degree. C. The improvement comprises utilizing a reactor that includes an initial "dense" zone and a downstream "dilute" zone. In the dense zone, a fuel is burned, reactants and recirculated iron oxide particles are heated, ferric chloride is vaporized and at least 50% of the ferric chloride is converted to chlorine and iron oxide. A solids volume fraction from 0.3 to 0.6 and a superficial gas velocity from 0.15 to 0.6 meters/second are maintained in the dense zone. In the downstream dilute zone, a solids fraction from 0.005 to 0.05 is maintained, along with a superficial gas velocity from 1.5 to 6 meters/second which is from 5 to 25 times the superficial gas velocity in the dense zone, and the conversion of ferric chloride is continued to greater than 95% completion.
公开/授权文献
- US5889254A Method and apparatus for Nd: YAG hardsurfacing 公开/授权日:1999-03-30