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US4208394A Commercial production of transition metal sulfides from their halides 失效
从其卤化物商业生产过渡金属硫化物

Commercial production of transition metal sulfides from their halides
Abstract:
Sulfides of Group IVb and Vb transition metals are produced by reacting their halides with carbon disulfide. The reactions can be between liquid or gaseous halides and liquid or gaseous carbon disulfide. The reaction products are formed and recovered as solids and the other reaction product, carbon tetrahalide, is carried off as a gas and recovered. A specific example is the production of titanium disulfide by reacting titanium tetrachloride with carbon disulfide.
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