发明授权
US4216341A Selective hydrogenation of certain nitroaromatic hydroxy substituted
acetylenes over a heterogeneous RuS.sub.2 catalyst
失效
某些硝基芳族羟基取代的乙炔在异质RuS2催化剂上的选择性加氢
- 专利标题: Selective hydrogenation of certain nitroaromatic hydroxy substituted acetylenes over a heterogeneous RuS.sub.2 catalyst
- 专利标题(中): 某些硝基芳族羟基取代的乙炔在异质RuS2催化剂上的选择性加氢
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申请号: US958161申请日: 1978-11-06
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公开(公告)号: US4216341A公开(公告)日: 1980-08-05
- 发明人: Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
- 申请人: Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
- 申请人地址: PA Pittsburgh
- 专利权人: Gulf Research & Development Company
- 当前专利权人: Gulf Research & Development Company
- 当前专利权人地址: PA Pittsburgh
- 主分类号: B01J27/045
- IPC分类号: B01J27/045 ; C07C79/22 ; C07C85/11 ; C07C85/24
摘要:
Nitroaromatic hydroxy substituted acetylene compounds wherein both the nitro and acetylene groups are directly connected to aromatic ring carbon atoms are hydrogenated in an inert solvent to selectively reduce the nitro function over a ruthenium disulfide catalyst. Of particular interest is the preparation of aminophenylacetylene from nitrophenyl hydroxy substituted acetylene.
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