发明授权
- 专利标题: Preparation of methoxy-methyl melamines
- 专利标题(中): 甲氧基甲基三聚氰胺的制备
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申请号: US51851申请日: 1979-06-25
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公开(公告)号: US4223141A公开(公告)日: 1980-09-16
- 发明人: Hans Honel , Karlfried Keller , Walter Michel , Manfred Schon
- 申请人: Hans Honel , Karlfried Keller , Walter Michel , Manfred Schon
- 申请人地址: DEX Frankfurt am Main
- 专利权人: Cassella Aktiengesellschaft
- 当前专利权人: Cassella Aktiengesellschaft
- 当前专利权人地址: DEX Frankfurt am Main
- 优先权: DEX2839713 19780913
- 主分类号: C07D251/64
- IPC分类号: C07D251/64 ; C08G12/42
摘要:
This invention relates to a process for the manufacture of methanol-etherified methylolmelamines which are largely monomeric containing more than 5 mols of formaldehyde and more than 4 mols of methyl-etherified methylol groups, per mol of melamine, and having a viscosity of less than 20 pascal-seconds at 25.degree. C. and a solids content of at least 95%, comprising (a) methylolating melamine with formaldehyde at a molar melamine:formaldehyde ratio of 1:6.5 to 1:8 for 11/2 to 5 hours at 50.degree. C. to 85.degree. C., with the formaldehyde source being an aqueous solution of formalin containing 30 to 50% by weight of formaldehyde and having a pH of 6.7 to 7.3, and (b) etherifying the resulting suspension of methylolmelamine with 15 to 30 mols of methanol per mol of melamine at temperatures of 30.degree. C. to 60.degree. C. in the presence of a strong acid.
公开/授权文献
- US6027276A Scaffolding node 公开/授权日:2000-02-22