发明授权
- 专利标题: Process for reacting sulfuric acid and an aromatic hydrocarbon to purify a disulfonic acid product of an aromatic hydrocarbon
- 专利标题(中): 使硫酸和芳烃反应以净化芳族烃的二磺酸产物的方法
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申请号: US171450申请日: 1980-07-23
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公开(公告)号: US4302403A公开(公告)日: 1981-11-24
- 发明人: Kenneth G. Reabe , Hans Dressler , Frederick M. Covelli
- 申请人: Kenneth G. Reabe , Hans Dressler , Frederick M. Covelli
- 申请人地址: PA Pittsburgh
- 专利权人: Koppers Company, Inc.
- 当前专利权人: Koppers Company, Inc.
- 当前专利权人地址: PA Pittsburgh
- 主分类号: C07C309/29
- IPC分类号: C07C309/29 ; C07C143/24
摘要:
Unreacted sulfuric acid contained in a disulfonic acid product of an aromatic hydrocarbon that is produced from the reaction of the aromatic hydrocarbon or the mono-sulfonic acid of the aromatic hydrocarbon with a strong sulfonating agent is removed from the disulfonic acid product by reacting the sulfuric acid with additional aromatic hydrocarbon to produce the mono-sulfonic acid of the aromatic compound. The disulfonic acid product of the aromatic hydrocarbon containing sulfuric acid is reacted with the aromatic hydrocarbon at a molar ratio of aromatic hydrocarbon to sulfuric acid in the range of about 0.25 to around 2 and at a temperature in the range of 130.degree. to 200.degree. C. to obviate the need to remove any water formed during the course of the reaction.