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US4302566A Preparation of ethylene copolymers in fluid bed reactor 失效
在流化床反应器中制备乙烯共聚物

Preparation of ethylene copolymers in fluid bed reactor
摘要:
Ethylene copolymers having a density of .gtoreq.0.91 to .ltoreq.0.96 and a melt flow ratio of .gtoreq.22 to .ltoreq.32 are readily produced in a low pressure gas phase process at a productivity of .gtoreq.50,000 pounds of polymer per pound of Ti with a particulate catalyst diluted with an inert carrier material and formed from selected organo aluminum compounds and a precursor composition of the formula:Mg.sub.m Ti.sub.1 (OR).sub.n X.sub.p [ED].sub.qwherein ED is a selected electron donor compound.m is .gtoreq.0.5 to .ltoreq.56n is 0 or 1p is .gtoreq.6 to .ltoreq.116q is .gtoreq.2 to .ltoreq.85R is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, andX is selected from the group consisting of Cl, Br, I, or mixtures thereof.
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