发明授权
US4309360A Process for the production of
bis-[O-(1-alkylthioethylimino)-N-methylcarbamyl]N,N'-sulfides
失效
制备双 - [O-(1-烷硫基乙基亚氨基)-N-甲基氨基甲酰基] N,N'-硫化物的方法
- 专利标题: Process for the production of bis-[O-(1-alkylthioethylimino)-N-methylcarbamyl]N,N'-sulfides
- 专利标题(中): 制备双 - [O-(1-烷硫基乙基亚氨基)-N-甲基氨基甲酰基] N,N'-硫化物的方法
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申请号: US156965申请日: 1980-06-06
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公开(公告)号: US4309360A公开(公告)日: 1982-01-05
- 发明人: Jean-Pierre Ledouble , Klaus Muller
- 申请人: Jean-Pierre Ledouble , Klaus Muller
- 申请人地址: NY Ardsley
- 专利权人: Ciba-Geigy Corporation
- 当前专利权人: Ciba-Geigy Corporation
- 当前专利权人地址: NY Ardsley
- 优先权: CHX5670/79 19790618
- 主分类号: A01N47/24
- IPC分类号: A01N47/24 ; A01N37/18 ; A01N41/12 ; C07C67/00 ; C07C325/00 ; C07C381/08 ; C07C119/18
摘要:
A process for the production of bis-[O-(1-alkylthioethylimino)-N-methylcarbamyl]-N,N-sulfides of the formula I ##STR1## wherein R is a straight-chain or branched alkyl group of 1 to 5 carbon atoms, by reacting a O-(1-alkylthioethylimino)-N-methylcarbamate of the formula ##STR2## wherein R is as defined above, in the presence of a base, with sulfur dichloride or sulfur monochloride in an inert solvent, which process comprises carrying out said reaction in the presence of 0.01 to 0.5 mole of a compound selected from the group consisting of N,N-dialkylformamides, each containing 1 to 4 carbon atoms in the alkyl moieties, N-methylpyrrolidone, dimethyl sulfoxide, phosphoric acid tris-N,N-dimethylamide and tetramethyl urea, per mole of O-(1-alkylthioethylimino)-N-methylcarbamate of the formula II.The bis-[O-(1-alkylthioethylimino)-N-methylcarbamyl]-N,N'-sulfides of the above formula possess insecticidal properties and are suitable in particular for controlling pests of cotton plants and bluebottles.
公开/授权文献
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