发明授权
US4312995A Copolymerizable ultraviolet light absorber members which are .alpha.,.beta.
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失效
可共聚的紫外光吸收体,它们是2-羟基,烷氧基,羟甲基二苯甲酮的α,β-不饱和二羧酸半酯
- 专利标题: Copolymerizable ultraviolet light absorber members which are .alpha.,.beta. -
- 专利标题(中): 可共聚的紫外光吸收体,它们是2-羟基,烷氧基,羟甲基二苯甲酮的α,β-不饱和二羧酸半酯
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申请号: US168224申请日: 1980-07-10
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公开(公告)号: US4312995A公开(公告)日: 1982-01-26
- 发明人: Eugene S. Barabas , Prakash Mallya , Stanley J. Gromelski, Jr.
- 申请人: Eugene S. Barabas , Prakash Mallya , Stanley J. Gromelski, Jr.
- 申请人地址: NY New York
- 专利权人: GAF Corporation
- 当前专利权人: GAF Corporation
- 当前专利权人地址: NY New York
- 主分类号: C07C59/84
- IPC分类号: C07C59/84
摘要:
This invention relates to copolymerizable ultraviolet light absorber monomers which are .alpha.,.beta.-unsaturated dicarboxylic half-esters of 2-hydroxy,alkoxy,methylolbenzophenone intermediate compounds. The monomers have the formula: ##STR1## where R is alkyl C.sub.1 -C.sub.8, and n is 1 or 2, andY is a half-acyl radical of a .alpha.,.beta.-unsaturated dicarboxylic acid selected from the group of maleic and itaconic acids.The monomers herein are made by monoesterifying intermediate compounds, prepared by converting a 2-hydroxy,alkoxy,benzophenone to the corresponding methylol derivative by a formylation reaction, with the anhydride of the desired acid.In the preferred embodiments of the invention, the alkoxy group is methoxy in the 4-position, the methylol group which is half-esterified is a monomethylol group located at the 3- or 5- position of the phenyl ring containing the hydroxy group, and the acid anhydride is maleic anhydride.Copolymerization of the monomers herein with vinyl monomers provide improved ultraviolet light stable copolymers for industrial and commercial applications.
公开/授权文献
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