发明授权
US4351961A 2-(2',2'-Dichloro-3',3',3'-trifluoropropyl)- and
2-(2',2',3'-trichloro-3',3'-difluoropropyl)-4-chlorocyclobutan-1-ones
失效
2-(2',2'-二氯-3',3',3'-三氟丙基)和2-(2',2',3'-三氯-3',3'-二氟丙基)-4-氯环丁烷 -1
- 专利标题: 2-(2',2'-Dichloro-3',3',3'-trifluoropropyl)- and 2-(2',2',3'-trichloro-3',3'-difluoropropyl)-4-chlorocyclobutan-1-ones
- 专利标题(中): 2-(2',2'-二氯-3',3',3'-三氟丙基)和2-(2',2',3'-三氯-3',3'-二氟丙基)-4-氯环丁烷 -1
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申请号: US210892申请日: 1980-11-28
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公开(公告)号: US4351961A公开(公告)日: 1982-09-28
- 发明人: Pierre Martin , Eginhard Steiner , Daniel Bellus
- 申请人: Pierre Martin , Eginhard Steiner , Daniel Bellus
- 申请人地址: NY Ardsley
- 专利权人: Ciba-Geigy Corporation
- 当前专利权人: Ciba-Geigy Corporation
- 当前专利权人地址: NY Ardsley
- 优先权: CHX10869/79 19791207
- 主分类号: C07C69/63
- IPC分类号: C07C69/63 ; C07C45/00 ; C07C45/45 ; C07C45/67 ; C07C49/457 ; C07C51/00 ; C07C53/21 ; C07C53/42 ; C07C53/50 ; C07C67/00 ; C07C253/00 ; C07C255/10
摘要:
Compounds of the formula I ##STR1## wherein X is chlorine or fluorine, are suitable for producing 2,2-dimethyl-3-(2'-chloro-3',3',3'-trifluoroprop-1'-en-1'-yl)- and 2,2-dimethyl-3-(2',3'-dichloro-3',3'-difluoroprop-1'-en-1'-yl)-cyclopropanecarboxylic acids and insecticidally effective esters thereof (pyrethroids). The cyclobutanones (I) can be produced by the addition reaction of 2,4,4,5-tetrachloro-5,5-difluoro- or 2,4,4-trichloro-5,5,5-trifluoropentane-1-carboxylic acid chloride with isobutylene, and rearrangement of the resulting 2-chloro-2-(2',2',3'-trichloro-3',3'-difluoropropyl)- or 2-chloro-2-(2',2'-dichloro-3',3',3'-trifluoropropyl)-3,3-dimethylcyclobutan-1-one in the presence of catalysts.
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