发明授权
US4354020A Continuous preparation of polycaprolactam in vertical tubular reactor
失效
在垂直管式反应器中连续制备聚己内酰胺
- 专利标题: Continuous preparation of polycaprolactam in vertical tubular reactor
- 专利标题(中): 在垂直管式反应器中连续制备聚己内酰胺
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申请号: US143591申请日: 1980-04-24
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公开(公告)号: US4354020A公开(公告)日: 1982-10-12
- 发明人: Rudi-Heinz Rotzoll , Paul Matthies , Guenter Valentin , Werner Hoerauf
- 申请人: Rudi-Heinz Rotzoll , Paul Matthies , Guenter Valentin , Werner Hoerauf
- 申请人地址: DEX
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX
- 优先权: DEX2918828 19790510
- 主分类号: C08G69/00
- IPC分类号: C08G69/00 ; B01J19/18 ; C08G69/04 ; C08G69/16
摘要:
A process for the continuous preparation of polycaprolactam, which comprises polymerizing .epsilon.-caprolactam in a vertical tubular reactor through which the .epsilon.-caprolactam flows downward, wherein the .epsilon.-caprolactam is partially polymerized, at a nylon-forming temperature, in a mechanically mixed zone, the reaction mixture is circulated through a heat exchange zone in the lower part of the mechanically mixed reaction zone, and is polymerized further, in additional heat exchange zones, until the desired degree of polymerization is reached, and poly-.epsilon.-caprolactam is then discharged as a melt, and an apparatus for carrying out the process.
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