发明授权
US4354020A Continuous preparation of polycaprolactam in vertical tubular reactor 失效
在垂直管式反应器中连续制备聚己内酰胺

Continuous preparation of polycaprolactam in vertical tubular reactor
摘要:
A process for the continuous preparation of polycaprolactam, which comprises polymerizing .epsilon.-caprolactam in a vertical tubular reactor through which the .epsilon.-caprolactam flows downward, wherein the .epsilon.-caprolactam is partially polymerized, at a nylon-forming temperature, in a mechanically mixed zone, the reaction mixture is circulated through a heat exchange zone in the lower part of the mechanically mixed reaction zone, and is polymerized further, in additional heat exchange zones, until the desired degree of polymerization is reached, and poly-.epsilon.-caprolactam is then discharged as a melt, and an apparatus for carrying out the process.
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