Invention Grant
US4376224A Aluminum chloride catalyzed isomerization of sym-octahydrophenanthrene to sym-octahydroanthracene with acyl peroxide 失效
氯化铝催化异构化对偶八氢菲与对 - 八氢蒽与酰基过氧化物

  • Patent Title: Aluminum chloride catalyzed isomerization of sym-octahydrophenanthrene to sym-octahydroanthracene with acyl peroxide
  • Patent Title (中): 氯化铝催化异构化对偶八氢菲与对 - 八氢蒽与酰基过氧化物
  • Application No.: US372059
    Application Date: 1982-04-26
  • Publication No.: US4376224A
    Publication Date: 1983-03-08
  • Inventor: William T. Gormley
  • Applicant: William T. Gormley
  • Applicant Address: PA Pittsburgh
  • Assignee: Koppers Company, Inc.
  • Current Assignee: Koppers Company, Inc.
  • Current Assignee Address: PA Pittsburgh
  • Main IPC: C07C5/22
  • IPC: C07C5/22 C07C5/24 C07C5/30
Aluminum chloride catalyzed isomerization of sym-octahydrophenanthrene
to sym-octahydroanthracene with acyl peroxide
Abstract:
A method is disclosed for promoting isomerization of sym-octahydrophenanthrene (s-OHP) to sym-octahydroanthracene (s-OHA) in the presence of a catalyst provided by aluminum chloride or aluminum bromide, or a mixture of these two compounds. The rate of isomerization is increased by having the reaction run in the presence of an acyl peroxide such as benzoyl peroxide or lauroyl peroxide.
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