发明授权
- 专利标题: Process for producing propylene block copolymers
- 专利标题(中): 制备丙烯嵌段共聚物的方法
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申请号: US255005申请日: 1981-04-17
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公开(公告)号: US4433110A公开(公告)日: 1984-02-21
- 发明人: Kazuo Baba , Shyozo Kawamata , Yoshiharu Fukui , Seiichiro Ima , Tatsuya Miyatake
- 申请人: Kazuo Baba , Shyozo Kawamata , Yoshiharu Fukui , Seiichiro Ima , Tatsuya Miyatake
- 申请人地址: JPX Osaka
- 专利权人: Sumitomo Chemical Company, Limited
- 当前专利权人: Sumitomo Chemical Company, Limited
- 当前专利权人地址: JPX Osaka
- 优先权: JPX55-53450 19800421; JPX55-70451 19800526
- 主分类号: C08F297/08
- IPC分类号: C08F297/08
摘要:
A propylene block copolymer produced by polymerizing propylene, ethylene and an .alpha.-olefin having 4 to 8 carbon atoms in two stages with a Zieglar-Natta catalyst by a process which comprises (A) supplying propylene and ethylene in the first stage and propylene and the .alpha.-olefin in the second stage, or (B) supplying propylene and the .alpha.-olefin in the first stage and propylene and ethylene in the second stage, to the polymerization system, wherein the amounts of propylene and ethylene supplied in the first stage of (A) or in the second stage of (B) are 90 to 99 wt % and 10 to 1 wt % based on the total amount of propylene and ethylene supplied in the first stage of (A) or in the second stage of (B), respectively, the amounts of propylene and the .alpha.-olefin supplied in the second stage of (A) or in the first stage of (B) are 60 to 98 wt % and 40 to 2 wt % based on the total amount of propylene and the .alpha.-olefin supplied in the second stage of (A) or in the first stage of (B), respectively, and the amounts of copolymers formed in the first and second stages are 20 to 90 wt % and 80 to 10 wt % based on the final block copolymer, respectively.
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