发明授权
- 专利标题: Manufacture of aryl esters
- 专利标题(中): 芳基酯的制造
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申请号: US441360申请日: 1982-11-15
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公开(公告)号: US4465633A公开(公告)日: 1984-08-14
- 发明人: Anil B. Goel , Peter E. Throckmorton
- 申请人: Anil B. Goel , Peter E. Throckmorton
- 申请人地址: KY Ashland
- 专利权人: Ashland Oil, Inc.
- 当前专利权人: Ashland Oil, Inc.
- 当前专利权人地址: KY Ashland
- 主分类号: C07C69/035
- IPC分类号: C07C69/035 ; B01J23/00 ; B01J31/04 ; C07B61/00 ; C07C67/055 ; C07C69/017 ; C11C3/02
摘要:
A process is described for the manufacture of aryl esters such as phenyl esters by liquid phase reaction of an aromatic compound such as benzene with molecular oxygen in the presence of a carboxylic acid preferably having 6 or more carbon atoms over a catalyst composed essentially of a compound of palladium, a compound of antimony and a compound of at least one member selected from the group consisting of chromium, cobalt, nickel, manganese, iron, and tin wherein the aromatic compound is added continuously to the reaction and water formed in the reaction is rapidly and continuously removed from the reaction zone.
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