发明授权
US4482703A Thermosetting resin composition comprising dicyanamide and polyvalent
imide
失效
包含二氰胺和多价酰亚胺的热固性树脂组合物
- 专利标题: Thermosetting resin composition comprising dicyanamide and polyvalent imide
- 专利标题(中): 包含二氰胺和多价酰亚胺的热固性树脂组合物
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申请号: US435766申请日: 1982-10-20
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公开(公告)号: US4482703A公开(公告)日: 1984-11-13
- 发明人: Akio Takahashi , Takeshi Shimazaki , Motoyo Wajima , Hirosada Morishita
- 申请人: Akio Takahashi , Takeshi Shimazaki , Motoyo Wajima , Hirosada Morishita
- 申请人地址: JPX Tokyo
- 专利权人: Hitachi, Ltd.
- 当前专利权人: Hitachi, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX56-168787 19811023
- 主分类号: C08G73/00
- IPC分类号: C08G73/00 ; C08G73/06 ; C08G73/12 ; C09D179/08 ; C08G73/10
摘要:
A thermosetting resin composition comprises (A) at least one dicyanamide compound and (B) at least one polyvalent imide having one or more unsaturated bonds and, if necessary (C) at least one polymerizable compound of epoxy compounds, phenolic compounds and triallyl isocyanurate compounds. A thermosetting prepolymer can be obtained by subjecting the composition to a preliminary reaction with heating to the B stage and this prepolymer can give a cured product having excellent heat resistance of class C and flexibility. An exemplary composition containing 60 parts by wt. of 4,4'-dicyanomidodiphenylmethane and 40 parts by wt. of N,N'-4,4'-diphenylmethane bismaleimide dissolved in methyl Cellosolve is reacted at 70.degree. to 110.degree. C. for about 40 minutes to obtain a prepolymer soluble in methyl ethyl ketone. This prepolymer when admixed with 2-ethyl-4-methyl-imidazole and after removal of the methyl cellusolve will form an insoluble and infusible cured product upon heating at temperatures on the order of 170.degree. to 200.degree. C. for about 80 minutes. The resin composition when admixed with a solvent, is useful for impregnation and when used as a powder, it is useful as a molding resin.
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