发明授权
- 专利标题: Removal of the catalyst from polyphenylene ethers
- 专利标题(中): 从聚苯醚中除去催化剂
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申请号: US518612申请日: 1983-07-29
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公开(公告)号: US4482705A公开(公告)日: 1984-11-13
- 发明人: Juergen Hambrecht , Rudi W. Reffert , Volker Muench , Adolf Echte , Johann Swoboda
- 申请人: Juergen Hambrecht , Rudi W. Reffert , Volker Muench , Adolf Echte , Johann Swoboda
- 申请人地址: DEX
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX
- 优先权: DEX3228662 19820731
- 主分类号: C08G65/46
- IPC分类号: C08G65/46
摘要:
High molecular weight polyphenylene ethers are prepared from monohydric phenols by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a copper salt and an organic amine by a method wherein the metal component of the catalyst is separated off, after the polymerization, by the addition of a polymeric polycarboxylic acid which is essentially composed of unsaturated monofunctional or difunctional carboxylic acids and/or their anhydrides.Advantageously, the polymeric polycarboxylic acids used are homopolymers or copolymers of (a) from 50 to 100% by weight of one or more unsaturated monofunctional acids of 3 to 10 carbon atoms and/or one or more difunctional acids or their anhydrides of 4 to 6 carbon atoms and from 0 to 50% by weight of one or more monomers which do not possess an acid function and can be copolymerized with (a).