发明授权
US4518729A Solutions of isocyanato-isocyanurates in plasticizers for polyvinyl chloride, a process for their production and their use as adhesion-improving additives in coating compositions based on plasticized polyvinyl chloride 失效
异氰酸根合异氰脲酸酯在聚氯乙烯增塑剂中的应用,它们的生产方法及其作为基于增塑聚氯乙烯的涂料组合物中的粘合改进添加剂的用途

Solutions of isocyanato-isocyanurates in plasticizers for polyvinyl
chloride, a process for their production and their use as
adhesion-improving additives in coating compositions based on
plasticized polyvinyl chloride
摘要:
The present invention relates to solutions of isocyanato-isocyanurates based on mixtures of (i) 2,4- and/or 2,6-diisocyanato-toluene and (ii) 2,2'-, 2,4'- and/or 4,4'-diisocyanato-diphenyl methane in a molar ratio of (i) to (ii) of about 5:1 to 1:3, in plasticizers for polyvinyl chloride wherein the isocyanato-isocyanurates comprise about 1 to 50% by weight of the solution. The present invention also relates to a process for preparing these solutions which comprise partially trimerizing the isocyanate groups of the above diisocyanates using catalysts which accelerate the trimerization of isocyanate groups, the reaction either being conducted in the presence of plasticizers for polyvinyl chloride or the reaction product being dissolved in a plasticizer of this type, optionally after the separation of excess, unreacted diisocyanate.In addition, the present invention relates to the use of these solutions as adhesion-improving additives for coating compositions based on polyvinyl chloride. Besides improved adhesion, these compositions also demonstrate improved resistance to discoloration during thermal processing.
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