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US4522755A Metal phthalocyanine intermediates for the preparation of polymers 失效
用于制备聚合物的金属酞菁中间体

Metal phthalocyanine intermediates for the preparation of polymers
Abstract:
Metal 4, 4', 4", 4"'-tetracarboxylic phthalocyanines (MPTC) are prepared by reaction of trimellitic anhydride, a salt or hydroxide of the desired metal (or the metal in powdered form), urea and a catalyst. A purer form of MPTC is prepared than heretofore. These tetracarboxylic acids are then polymerized by heat to sheet polymers which have superior heat and oxidation resistance. The metal is preferably a divalent metal having an atomic radius close to 1.35.ANG..
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