发明授权
- 专利标题: Process for the preparation of polyolefins
- 专利标题(中): 制备聚烯烃的方法
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申请号: US559838申请日: 1983-12-08
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公开(公告)号: US4542199A公开(公告)日: 1985-09-17
- 发明人: Walter Kaminsky , Heinrich Hahnsen , Klaus Kulper , Rudiger Woldt
- 申请人: Walter Kaminsky , Heinrich Hahnsen , Klaus Kulper , Rudiger Woldt
- 申请人地址: DEX
- 专利权人: Hoechst Aktiengesellschaft
- 当前专利权人: Hoechst Aktiengesellschaft
- 当前专利权人地址: DEX
- 优先权: DEX3127133 19810709
- 主分类号: C08F4/00
- IPC分类号: C08F4/00 ; C08F4/60 ; C08F4/64 ; C08F4/642 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F210/16
摘要:
The invention relates to a process for the preparation of polyolefins by polymerizing olefins of the formula CH.sub.2 CHR in which R=H or C.sub.1 -C.sub.10 alkyl, on their own or as a mixture, if appropriate together with C.sub.4 -C.sub.12 .alpha.,.omega.-diolefins, in solvents, liquid monomers or the gas phase, at temperatures between -50.degree. and 200.degree. C., using a catalyst system composed of a soluble, halogen-containing transition metal compound of the general formula(cyclopentadienyl).sub.2 Me R Halin which R is cyclopentadienyl or a C.sub.1 -C.sub.6 alkyl radical or a halogen, in particular chlorine, Me is a transition metal, in particular zirconium, and Hal is a halogen, in particular chlorine, and a compound, containing aluminum, of the aluminoxane type having the general formulaeAl.sub.2 OR.sub.4 (Al(R)--O).sub.nfor a linear aluminoxane and/or(Al(R)--O).sub.n+2for a cyclic aluminoxane, in which n is a number from 4 to 20 and R is a methyl or ethyl radical, preferably a methyl radical.
公开/授权文献
- US5627307A Method for measuring intensity index of odor 公开/授权日:1997-05-06
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