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US4594461A Preparation of trimethylolalkanes from alkanals and formaldehyde 失效
从链烷和甲醛制备三羟甲基烷烃

Preparation of trimethylolalkanes from alkanals and formaldehyde
摘要:
Trimethylolalkanes are prepared by reacting an n-alkanal with formaldehyde and a trialkylamine in aqueous solution and then hydrogenating the product, by a method in which from 2.2 to 4.5 moles of formaldehyde and from 0.6 to 3 moles of trialkylamine are used per mole of the alkanal, and the reaction mixture is worked up by distillation either before or after the hydrogenation.
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