发明授权
- 专利标题: One-step hydrogenation/esterification of benzyloxy phenoxy propanoic acid
- 专利标题(中): 苄氧基苯氧基丙酸的一步氢化/酯化
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申请号: US804963申请日: 1985-12-05
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公开(公告)号: US4613677A公开(公告)日: 1986-09-23
- 发明人: Stanley B. Mirviss
- 申请人: Stanley B. Mirviss
- 申请人地址: CT Westport
- 专利权人: Stauffer Chemical Company
- 当前专利权人: Stauffer Chemical Company
- 当前专利权人地址: CT Westport
- 主分类号: C07C69/712
- IPC分类号: C07C69/712 ; C07C69/76
摘要:
The invention is directed to the one-step hydrogenation/esterification of arylmethyleneoxyaryloxy alkanoic acids to produce (hydroxyphenoxy) carboxylates. The process comprises the hydrogenation and esterification of the aryloxy alkanoic acid in the presence of a palladium hydrogenation catalyst and an acidic esterification catalyst preferably utilizing the alcohol for the esterification as the hydrogenation solvent. The acid serves the dual role of hydrogenation promoter and esterification catalyst.
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