发明授权
US4613677A One-step hydrogenation/esterification of benzyloxy phenoxy propanoic acid 失效
苄氧基苯氧基丙酸的一步氢化/酯化

One-step hydrogenation/esterification of benzyloxy phenoxy propanoic acid
摘要:
The invention is directed to the one-step hydrogenation/esterification of arylmethyleneoxyaryloxy alkanoic acids to produce (hydroxyphenoxy) carboxylates. The process comprises the hydrogenation and esterification of the aryloxy alkanoic acid in the presence of a palladium hydrogenation catalyst and an acidic esterification catalyst preferably utilizing the alcohol for the esterification as the hydrogenation solvent. The acid serves the dual role of hydrogenation promoter and esterification catalyst.
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