发明授权
US4632769A Ethylene copolymer viscosity index improver-dispersant additive useful
in oil compositions
失效
用于油组合物的乙烯共聚物粘度指数改进剂 - 分散剂
- 专利标题: Ethylene copolymer viscosity index improver-dispersant additive useful in oil compositions
- 专利标题(中): 用于油组合物的乙烯共聚物粘度指数改进剂 - 分散剂
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申请号: US679471申请日: 1984-12-07
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公开(公告)号: US4632769A公开(公告)日: 1986-12-30
- 发明人: Antonio Gutierrez , Darrell W. Brownawell , Ricardo Bloch , Jack E. Johnston
- 申请人: Antonio Gutierrez , Darrell W. Brownawell , Ricardo Bloch , Jack E. Johnston
- 申请人地址: NJ Florham Park
- 专利权人: Exxon Research & Engineering Co.
- 当前专利权人: Exxon Research & Engineering Co.
- 当前专利权人地址: NJ Florham Park
- 主分类号: C08F8/32
- IPC分类号: C08F8/32 ; C10M145/10 ; C10M133/16
摘要:
Oil soluble viscosity index improving ethylene copolymers, such as copolymers of ethylene and propylene; and ethylene, propylene and diolefin; etc., are reacted or grafted with ethylenically unsaturated carboxylic acid moieties, preferably maleic anhydride moieties, and reacted with polyamines having two or more primary amine groups and a C.sub.22 to C.sub.28 olefin carboxylic acid component, preferably alkylene polyamine and alkenyl succinic anhydride, respectively. These reactions can permit the incorporation of varnish inhibition and dispersancy into the ethylene copolymer while inhibiting cross-linking with resulting viscosity increase, haze or gelling. The aforesaid grafting reaction may be carried out thermally, or more preferably with a free radical initiator such as a peroxide in a mineral lubricating oil, in which case the olefin carboxylic acid component, preferably also acts to solubilize insoluble compounds formed by side reactions, such as maleic anhydride grafted oil molecules reacted with amine, to thereby inhibit haze formation, particularly when preparing oil concentrates of the V.I.-dispersant additive for later addition to lubricating oils.
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