发明授权
- 专利标题： Hydrogenolysis of polyalkylene glycols to produce monoethylene glycol monoalkyl ethers, monoethylene glycol and ethanol
- 专利标题（中）： 聚亚烷基二醇的氢解产生单乙二醇单烷基醚，单乙二醇和乙醇
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申请号： US736528申请日： 1985-05-21
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公开(公告)号： US4649225A公开(公告)日： 1987-03-10
- 发明人: William J. Bartley
- 申请人： William J. Bartley
- 申请人地址： CT Danbury
- 专利权人： Union Carbide Corporation
- 当前专利权人： Union Carbide Corporation
- 当前专利权人地址： CT Danbury
- 主分类号： C07C29/00
- IPC分类号： C07C29/00 ; C07C29/10 ; C07C29/60 ; C07C41/18 ; C07C43/13 ; C07C41/01 ; C07C27/00
摘要：
This invention relates to a process for selectively cleaving a polyalkylene glycol, e.g., diethylene glycol, containing at least one ether group therein at a carbon-to-oxygen covalent bond and independently at a carbon-to-carbon covalent bond by heating the polyalkylene glycol with molecular hydrogen in the presence of a hydrogenation catalyst containing iridium to produce at least one of monoethylene glycol monoethyl ether, monoethylene glycol monomethyl ether, monoethylene glycol and ethanol. Monoethylene glycol monoethyl ether can be produced in significant amounts by employing the process of this invention.
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