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US4657882A Supported olefin polymerization catalyst produced from a magnesium alkyl/organophosphoryl complex 失效
由烷基镁/有机磷酰基络合物制备的负载型烯烃聚合催化剂

Supported olefin polymerization catalyst produced from a magnesium
alkyl/organophosphoryl complex
摘要:
A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics, comprises the product formed by (a) complexing a magnesium alkyl composition with an organophosphoryl compound; (b) reacting the resulting stable complex with a compatible precipitation agent to form a solid component; and (c) reacting the resulting solid with a titanium (IV) compound and an electron donor compound in a suitable diluent.
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