发明授权
- 专利标题: Polymerization catalyst for ethylene homopolymerization
- 专利标题(中): 用于乙烯均聚的聚合催化剂
-
申请号: US471068申请日: 1983-03-07
-
公开(公告)号: US4684703A公开(公告)日: 1987-08-04
- 发明人: Burkhard E. Wagner , Frederick J. Karol , George L. Goeke , Robert J. Jorgensen , Nils Friis
- 申请人: Burkhard E. Wagner , Frederick J. Karol , George L. Goeke , Robert J. Jorgensen , Nils Friis
- 申请人地址: CT Danbury
- 专利权人: Union Carbide Corporation
- 当前专利权人: Union Carbide Corporation
- 当前专利权人地址: CT Danbury
- 主分类号: C08F2/34
- IPC分类号: C08F2/34 ; C08F4/02 ; C08F4/642 ; C08F4/654 ; C08F4/655 ; C08F110/02
摘要:
A catalyst formed from selected organo aluminum compounds and a precursor composition of the formulaMg.sub.m Ti.sub.l (OR).sub.n X.sub.p [ED].sub.qwhereinED is a selected electron donor compoundm is .gtoreq.0.5 to .ltoreq.56n is 0 or 1p is .gtoreq.6 to .ltoreq.116q is .gtoreq.2 to .ltoreq.85R is a C.sub.1 to C.sub.14, aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, andX is selected from the group consisting of Cl, Br, I, or mixtures thereof, which catalyst is in particulate form and diluted with an inert carrier material; a process for preparing such catalyst; a process for using said catalyst to readily prepare ethylene homopolymer having a density of about .gtoreq.0.958 to .ltoreq.0.972 and a melt flow ratio of .gtoreq.22 to .ltoreq.32 in a low pressure gas phase process at a productivity of .gtoreq.50,000 pounds of polymer per pound of Ti. Novel polymers and molded articles are prepared.
公开/授权文献
- US5948635A Totally Synthetic Affinity Reagents 公开/授权日:1999-09-07
信息查询