发明授权
- 专利标题: High molecular weight terpolymers of acrylamide, acrylic acid salts and alkylacrylamide
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申请号: US866724申请日: 1986-05-27
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公开(公告)号: US4694058A公开(公告)日: 1987-09-15
- 发明人: Donald B. Siano , Jan Bock
- 申请人: Donald B. Siano , Jan Bock
- 申请人地址: NJ Florham Park
- 专利权人: Exxon Research and Engineering Company
- 当前专利权人: Exxon Research and Engineering Company
- 当前专利权人地址: NJ Florham Park
- 主分类号: C08F8/12
- IPC分类号: C08F8/12 ; C08F220/70
摘要:
Novel water soluble copolymers of acrylamide, oil soluble higher alkylacrylamide and alkali metal acrylate have been found to provide efficient viscosification of water or brine. The process for synthesizing them relies on the complete solubilization of the water insoluble monomer into an aqueous solution of the water soluble monomer(s) by means of a suitable water soluble surfactant. A redox initiator system is used in conjunction with high monomer concentration and a low reaction temperature. The surfactant chosen and its concentration is one that produces a clear, uniform, homogeneous mixture in the presence of the monomers and gives a product which remains a clear uniform, homogeneous mixture with no phase separation as the reaction proceeds toward completion. The molecular weight of the resulting polymer after isolation from the surfactant is sufficiently high that it gives an intrinsic viscosity greater than about 12 dl/g.
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