发明授权
US4709767A Production process for manufacturing low molecular weight water soluble
acrylic polymers as drilling fluid additives
失效
制造低分子量水溶性丙烯酸聚合物作为钻井液添加剂的生产工艺
- 专利标题: Production process for manufacturing low molecular weight water soluble acrylic polymers as drilling fluid additives
- 专利标题(中): 制造低分子量水溶性丙烯酸聚合物作为钻井液添加剂的生产工艺
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申请号: US816290申请日: 1986-01-06
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公开(公告)号: US4709767A公开(公告)日: 1987-12-01
- 发明人: William Alexander
- 申请人: William Alexander
- 申请人地址: IL Arlington Heights
- 专利权人: American Colloid Company
- 当前专利权人: American Colloid Company
- 当前专利权人地址: IL Arlington Heights
- 主分类号: C08F20/06
- IPC分类号: C08F20/06 ; C09K8/24 ; E21B21/00
摘要:
Disclosed is a process for preparing relatively low molecular weight, water absorbing, acrylic polymers for use as drilling fluid additives by aqueous polymerization of (A) an acrylic monomer, such as acrylic acid neutralized 0 to 100 mole percent with, for example, ammonia, and/or an alkali such as Na.sub.2 O.sub.3, and/or an amine; with (B) acrylamide in a mole ratio of 70 to 100 mole percent (A) to 30:0 mole percent (B). The molecular weight is limited to 1,000 to 50,000, such as by adding a chain transfer agent to the polymerization mixture, to achieve excellent results as a drilling fluid additive. The monomer, such as partially neutralized acrylic acid, is polymerized in aqueous solution in the presence of a polymerization initiator without external heating while allowing water to evaporate off. A substantially dry water soluble polymer (less than 15 weight percent water) is achieved when polymerization is completed by utilizing the exothermic heat of polymerization and cross-linking to drive off water without the need for additional heating to obtain a dry solid.
公开/授权文献
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