发明授权
- 专利标题: Polymerization of olefinic hydrocarbons and complex-initiator therefor
- 专利标题(中): 烯烃的聚合和其引发剂
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申请号: US668070申请日: 1984-11-05
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公开(公告)号: US4713424A公开(公告)日: 1987-12-15
- 发明人: Ronald E. Brown
- 申请人: Ronald E. Brown
- 申请人地址: OK Bartlesville
- 专利权人: Phillips Petroleum Company
- 当前专利权人: Phillips Petroleum Company
- 当前专利权人地址: OK Bartlesville
- 主分类号: C07C2/88
- IPC分类号: C07C2/88 ; C08F36/04 ; C07C2/00
摘要:
A continuous, liquid phase method for producing a polymer having a predetermined number of conjugated diene units per molecule in which (a) a first monomer stream is contacted with an organo-lithium compound, in a manner to intimately mix increments of monomer, containing the predetermined number of moles of conjugated diene, with each mole of organo-lithium and continuously mix and move the mixture through a first, elongated reaction zone to react the predetermined number of moles of conjugated diene with one mole of organo-lithium, (b) mixing the effluent from (a) with an alkyl-substituted aromatic hydrocarbon, an organo-alkali metal of potassium, rubidium or cesium and a tertiary amine to form a complex-initiator of the aromatic hydrocarbon, the alkali metal and the amine, (c) mixing the effluent from (b) with a second stream of monomer, in a manner to intimately mix increments of monomer, containing the predetermined number of moles of conjugated diene, with each mole of complex-initiator and continuously mix and move the mixture through a second, elongated reaction zone and (d) mixing the effluent of (c) to produce to form a polymer comprising the predetermined number of conjugated diene units and the aromatic hydrocarbon. Preferably, a portion of the effluent from (d), containing complex-initiator, is cooled and recycled to (c) to cool the reaction and supply complex-initiator.
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